Graham's Law

A law of effusion.

Graham's law of effusion, was formulated by Scottish physical chemist Thomas Graham in 1846. Graham found experimentally that the rate of effusion of a gas is inversely proportional to the square root of the mass of its particles
Graham's law states that the rate of effusion of a gas is inversely proportional to the square root of its molecular weight. Thus, if the molecular weight of one gas is four times that of another, it would diffuse through a porous plug or escape through a small pinhole in a vessel at half the rate of the other. A complete theoretical explanation of Graham's law was provided years later by the kinetic theory of gases. Graham's law provides a basis for separating isotopes by diffusion — a method that came to play a crucial role in the development of the atomic bomb.