The Greeks believed amethyst gems could prevent intoxication, while medieval European soldiers wore amethyst amulets as protection in battle in the belief that amethysts heal people and keep them cool-headed. Beads of amethyst were found in Anglo-Saxon graves in England. Western Christian bishops wear an episcopal ring often set with an amethyst, an allusion to the description of the Apostles as "not drunk" at Pentecost in Acts 2:15.
In the 19th century, the color of amethyst was attributed to the presence of manganese. However, since it is capable of being greatly altered and even discharged by heat, the color was believed by some authorities to be from an organic source. Ferric thiocyanate has been suggested, and sulfur was said to have been detected in the mineral.
Amethyst is produced in abundance from the state of Minas Gerais in Brazil where it occurs in large geodes within volcanic rocks. Many of the hollow agates of southwestern Brazil and Uruguay contain a crop of amethyst crystals in the interior. Artigas, Uruguay and neighboring Brazilian state Rio Grande do Sul are large world producers exceeding in quantity Minas Gerais, as well as Mato Grosso, Espirito Santo, Bahia, and Ceará states, all amethyst producers of importance in Brazil.
It is also found and mined in South Korea. The largest opencast amethyst vein in the world is in Maissau, Lower Austria. Much fine amethyst comes from Russia, especially from near Mursinka in the Ekaterinburg district, where it occurs in drusy cavities in granitic rocks. Many localities in south India yield amethyst. One of the largest global amethyst producers is Zambia in southern Africa with an annual production of about 1000 tonnes.
Amethyst occurs at many localities in the United States. Among these may be mentioned: the Mazatzal Mountain region in Gila and Maricopa Counties, Arizona; Red Feather Lakes, near Ft Collins, Colorado; Amethyst Mountain, Texas; Yellowstone National Park; Delaware County, Pennsylvania; Haywood County, North Carolina; Deer Hill and Stow, Maine and in the Lake Superior region of Minnesota, Wisconsin and Michigan. Amethyst is relatively common in the Canadian provinces of Ontario and Nova Scotia. The largest amethyst mine in North America is located in Thunder Bay, Ontario